

This means, that all the gangue materials remain in the product sponge iron, called Direct Reduced Iron (DRI). Direct reduction processes can be classified by its kind of used reducing agent in gas-based processes and coal-based processes. Gas-based processes are shaft furnaces, retorts and fluidized beds.





By using thermogravimetric analysis the process and mechanism of iron ore reduced by biomass char were investigated and compared with those reduced by coal and coke. It is found that biomass char has a higher reactivity. The increase of carbon-to-oxygen mole ratio (C/O) can lead to the enhancement of reaction rate and reduction fraction, …



Direct reduction iron can also be used as melting material in casting process, super pellet in blast furnace ironmaking, coolant in converter steelmaking, and chemical reactant in copper making. In 2014, the global total output of direct reduction iron was 75,000,000 t, which accounted for 4.49% of global total output of crude steel. ...





The Coal-Ore-Direct-Iron-Reduction (Codir) Process combines features of the Waelz Kiln and the Krupp–Renn Process [74]. The Krupp–Renn is an iron ore reduction process designed for low-grade ores that at one time had over 40 commercial installations, but high energy costs and availability of higher-grade ores led to the …



Analogously, when the magnetite is reduced to wüstite the reaction at the magnetite/wüstite interface can be expressed as: (5) F e 3 O 4 + F e 2 + + 2 e − → 4 F e O In contrast, oxygen atoms must diffuse from the iron/wüstite interface to the iron/gas interface once a dense iron layer forms, Fig. 2 (b) [6, 18].Then, hydrogen reacts with …





This paper presents a novel and environmentally friendly production of direct reduced iron (DRI) technology using biomass as an additive agent in iron ore pellets and simulated biomass-derived syngas as the reducing agent. The effects of biomass addition on iron ore pellets reduction and consequent reduction kinetics in simulated biomass ...



1. Introduction. Approximately 10 % of industrial CO 2 emissions globally come from the steel industry [1], [2].The iron and steel industry are heavily reliant on coking coal resources, resulting in excessive CO 2 emissions [3], [4].Hydrogen will likely become a pivotal secondary global energy source in the 21st century [5].The gas-based shaft …







Hydrogen is projected to take over the role of reducing agent for iron oxides in direct reduction processes, and it can also be used as an alternative, more sustainable fuel in industrial furnaces. Importantly, the implementation of H 2 in different installations will affect the refractory lining, but wear mechanisms are not fully understood.



The iron-ores that are charged into the process go through fluidized bed reactors where they are heated and reduced to Direct Reduced Iron (DRI). The DRI is then charged into the melter gasifier where the final reduction and melting as well as the production of reducing gas by gasification of coal with oxygen takes place ( Schenk, 2011 ).





This mathematical evaluation focuses on iron ore ultra-fines for their use in a novel hydrogen-based fluidized bed direct reduction process. The benefits of such a process include reduced CO 2 emissions and energy consumption per ton of product, lower operational and capital expenditure, and a higher oxide yield. Typical samples of iron …



The employed fuels are natural gas and/or coal. The energy consumption is in the order of 10.4 GJ/t-DRI that is equivalent to 300 m 3 of natural gas per ton of reduced iron. The CO 2 emissions are quantified in the range 0.77–0.92 t of CO 2 per ton of steel. As a function of the employed reducing reactors, the systems are of four main types:



The technology can also be applied for the direct reduction of iron ore to eliminate the cost and energy-intensive agglomeration step of iron ore fines in the form of sintering or pelletizing. The Circored Process. The generic Circored process is based on the reduction behavior of iron ore, shown in Fig. 1.







Direct-reduced iron (DRI), also called sponge iron, is produced from direct reduction of iron ore (in the form of lumps, pellets or fines) by a reducing gas produced from natural gas or coal. The reducing gas is a mixture majority of hydrogen (H2) and carbon monoxide (CO) which acts as reducing agent. This process of directly reducing the iron ...





In addition, direct reduced iron has a well-defined chemical composition when compared with steel scrap and has efficient melting properties in the electric arc furnace. Consequently, there is a great increase in the demand for direct reduced iron in electric arc steel making. These attractive features have led to an increase in worldwide ...



The blast furnace and direct reduction processes have been the major iron production routes for various iron ores (i.e. goethite, hematite, magnetite, maghemite, siderite, etc.) in the past few decades, but the challenges of maintaining the iron and steel-making processes are enormous. The challenges, such as cumbersome production …



The chemical thermodynamics and phase transformation behavior of the reduction of hematite, magnetite and wüstite with hydrogen are depicted in Fig. 1 and Fig. 2.The solid phases at equilibrium (Fig. 2) were predicted as a function of the temperature and the feed hydrogen mole fraction n 0 H2 /(n 0 H2 + n 0 Fe2O3) where n 0 is the …





The remaining 18 % of direct reduced iron is produced through coal-based reducing agents in rotary kilns (ACCAR, DRC and Krupp Rein processes) or rotary hearth furnaces (Fastmet process) [29]. The scrap and DR iron are loaded in the cylindrical refractory lined electric arc furnace. The melting begins when electrical energy is supplied to the ...





Direct reduced iron with a higher metal ratio can be produced, if keeping appropriate proportion of biomass in the pellets. Fu et al. [85] studied different pellets under simulated rotary hearth furnace conditions. Bamboo char, coconut shell char and rice husk char were used in the iron ore-biomass pellets, achieving metallization rate of 95.56 ...



• Iron ore fines (0.1 – 2.0 mm) are dried and preheated in a CFB preheater up to 900 °C before being introduced into the first-stage CFB reactor for the primary reduction stage. • Fast prereduction to a reduction level of up to 80%. • Final reduction in bubbling FB reactor achieves reduction degrees in excess of 95%.





This paper presents the hydrogen reduction behaviour of industrial pellets designed for the efficient hydrogen based direct reduction. The pellets were provided with very low non ferrous oxides percentage (0.52 of basicity index) and with the absence on TiO 2 oxides. The pellets measured diameters in the range 1.14–1.72 cm and were …




